Xen has no awareness of 3D V-Cache. All 16 cores will be considered equal. Your vCPU may be on a 3D V-Cache core one millisecond, then on a no-3D V-Cache core the next.
If you really want to alter this, you can pin your VM to one group of cores or the other.
However, do not make the mistake of thinking of some of these cores as "performance cores" while the others not. The ones with 3D V-Cache will outperform the others on a wide variety of workloads despite not being able to turbo to the same degree.