@TeddyAstie Thanks for that - I was going off of other old XCP hosts I have had running that did show IOMMU info there, so I figured it wasn't working on these particular machines. I also had the the Intel GPU working on those hosts, which further supported my theory. I do have a USB controller passed through to the same VM and that works perfectly, basically native functionality, but from the research I was doing it was suggested USB controllers are way less bothered about imperfect passthrough.
I was able to find a ROM for my particular GPU, but I don't know what - if anything - I can do with it in XCP. I've found lots of info for QEMU and Proxmox, but I'm not sure they directly translate.
If there's nothing I can do for the moment then I can live without the GPU, running decode on the CPU isn't really taxing it that much. Appreciate you looking into it.